Mathematical modeling of 1,3-butadiene and methyl methacrylate emulsion copolymerization process

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dc.contributor.authorOliveira E.D.
dc.contributor.authorCasella E.L.
dc.contributor.authorAraujo O.
dc.contributor.authorGiudici R.
dc.date.accessioned2024-03-13T01:00:33Z
dc.date.available2024-03-13T01:00:33Z
dc.date.issued2014
dc.description.abstractA mathematical model for emulsion copolymerization process of 1,3-butadiene and methyl methacrylate is presented and validated with experimental data in a batch reactor. The model is able to explain the effects of changes in temperature, monomer-to-water ratio, emulsifier concentration, initiator concentration, and monomer feed composition on the time evolution of monomer conversion, average particle size, and pressure. Despite its simplicity and a reduced number of adjustable parameters, the model is capable of accounting for the basic features of emulsion copolymerization processes and can be used in engineering applications. © 2013 American Chemical Society.
dc.description.firstpage7343
dc.description.issuenumber18
dc.description.lastpage7351
dc.description.volume53
dc.identifier.doi10.1021/ie402990e
dc.identifier.issn1520-5045
dc.identifier.urihttps://dspace.mackenzie.br/handle/10899/36385
dc.relation.ispartofIndustrial and Engineering Chemistry Research
dc.rightsAcesso Restrito
dc.titleMathematical modeling of 1,3-butadiene and methyl methacrylate emulsion copolymerization process
dc.typeArtigo
local.scopus.citations2
local.scopus.eid2-s2.0-84900411737
local.scopus.subjectAdjustable parameters
local.scopus.subjectAverage particle size
local.scopus.subjectEmulsion copolymerization
local.scopus.subjectEngineering applications
local.scopus.subjectFeed compositions
local.scopus.subjectInitiator concentration
local.scopus.subjectMethyl methacrylates
local.scopus.subjectMonomer conversions
local.scopus.updated2024-05-01
local.scopus.urlhttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84900411737&origin=inward
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