Mathematical modeling of 1,3-butadiene and methyl methacrylate emulsion copolymerization process

Tipo
Artigo
Data de publicação
2014
Periódico
Industrial and Engineering Chemistry Research
Citações (Scopus)
2
Autores
Oliveira E.D.
Casella E.L.
Araujo O.
Giudici R.
Orientador
Título da Revista
ISSN da Revista
Título de Volume
Membros da banca
Programa
Resumo
A mathematical model for emulsion copolymerization process of 1,3-butadiene and methyl methacrylate is presented and validated with experimental data in a batch reactor. The model is able to explain the effects of changes in temperature, monomer-to-water ratio, emulsifier concentration, initiator concentration, and monomer feed composition on the time evolution of monomer conversion, average particle size, and pressure. Despite its simplicity and a reduced number of adjustable parameters, the model is capable of accounting for the basic features of emulsion copolymerization processes and can be used in engineering applications. © 2013 American Chemical Society.
Descrição
Palavras-chave
Assuntos Scopus
Adjustable parameters , Average particle size , Emulsion copolymerization , Engineering applications , Feed compositions , Initiator concentration , Methyl methacrylates , Monomer conversions
Citação
DOI (Texto completo)
10.1021/ie402990e
URI
https://dspace.mackenzie.br/handle/10899/36385
Coleções
Artigos de periódico