Tuning the interphase adhesion in high-density polyethylene–silica nanocomposites with ionic liquids

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dc.contributor.authorDonato K.Z.
dc.contributor.authorDonato R.K.
dc.contributor.authorZhigunov A.
dc.contributor.authorMauler R.S.
dc.contributor.authorSchrekker H.S.
dc.date.accessioned2024-03-12T23:53:12Z
dc.date.available2024-03-12T23:53:12Z
dc.date.issued2019
dc.description.abstract© 2019 Wiley Periodicals, Inc.This work addresses the use of ionic liquids (ILs) as multifunctional additives in the formation of high-density polyethylene (HDPE)/sol–gel silica nanocomposites via the melt-mixing process. Different approaches for nanocomposite formation were studied and compared, including (1) silica modification with ILs during the sol–gel process and further addition into the polymer matrix, (2) reactive mixing in which silica-IL filler was formed in situ, and (3) direct IL application in the melt-mixing chamber with nonmodi-fied silica xerogel and HDPE. The nanocomposites were characterized by thermogravimetric analyses, differential scanning calorimetry, scanning electron microscopy, dynamic thermomechanical analyses, transmission electron microscopy, and contact angle analyses. To improve the silica compatibilization with HDPE, we investigated imidazolium ILs that presented at least one nonpolar ionic counterpart. This permitted control of the silica structure, morphology, dispersion, and interfacial interactions, providing enhancements in thermomechanical properties.
dc.description.issuenumber17
dc.description.volume136
dc.identifier.doi10.1002/app.47366
dc.identifier.issn1097-4628
dc.identifier.urihttps://dspace.mackenzie.br/handle/10899/35269
dc.relation.ispartofJournal of Applied Polymer Science
dc.rightsAcesso Restrito
dc.subject.otherlanguageComposites
dc.subject.otherlanguageExtrusion
dc.subject.otherlanguageMorphology
dc.subject.otherlanguageSurfaces and interfaces
dc.subject.otherlanguageSynthesis and processing techniques
dc.titleTuning the interphase adhesion in high-density polyethylene–silica nanocomposites with ionic liquids
dc.typeArtigo
local.scopus.citations3
local.scopus.eid2-s2.0-85059512454
local.scopus.subjectDynamic thermomechanical analysis
local.scopus.subjectHigh density polyethylene(HDPE)
local.scopus.subjectInterfacial interaction
local.scopus.subjectMultifunctional additives
local.scopus.subjectNanocomposite formations
local.scopus.subjectSurfaces and interfaces
local.scopus.subjectSynthesis and processing
local.scopus.subjectThermomechanical properties
local.scopus.updated2024-05-01
local.scopus.urlhttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85059512454&origin=inward
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