Determination of kinetics parameters of thermal decomposition to BS and BD propellants Determinação dos parâmetros cinéticos de decomposição térmica para propelentes BS e BD

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dc.contributor.authorAndrade J.
dc.contributor.authorIha K.
dc.contributor.authorRocco J.A.F.F.
dc.contributor.authorFranco G.P.
dc.contributor.authorSuzuki N.
dc.contributor.authorSuarez-Iha M.E.V.
dc.date.accessioned2024-03-13T01:40:45Z
dc.date.available2024-03-13T01:40:45Z
dc.date.issued2007
dc.description.abstractThe purpose of this work was to determine the kinetics parameters of the thermal decomposition of a sample single-base (BS) and double-base (BD) propellants. The experimental data obtained by differential scanning calorimetry (DSC) were adjusted to the pseudo-first order kinetic model of Flynn, Wall and Ozawa. The respective parameters obtained are: BS REX 1200 (Ea) (2.3 ± 0.2) 102 kJ mol-1 and (A) 1.34 1025 min-1; BD-111 (Ea) (1.6 ± 0.1) 102 kJ mol-1 and (A) 3.31 1017 min-1. IR spectrum has confirmed the presence of salicilate in the double-base (BD) propellant and some correlations corroborate the conclusions about the decomposition mechanism.
dc.description.firstpage45
dc.description.issuenumber3
dc.description.lastpage50
dc.description.volume32
dc.identifier.doi10.1590/s0100-46702007000300007
dc.identifier.issn0100-4670
dc.identifier.urihttps://dspace.mackenzie.br/handle/10899/37696
dc.relation.ispartofEcletica Quimica
dc.rightsAcesso Aberto
dc.subject.otherlanguageKinetics
dc.subject.otherlanguagePropellants
dc.subject.otherlanguageThermal analysis
dc.titleDetermination of kinetics parameters of thermal decomposition to BS and BD propellants Determinação dos parâmetros cinéticos de decomposição térmica para propelentes BS e BD
dc.typeArtigo
local.scopus.citations4
local.scopus.eid2-s2.0-36949016238
local.scopus.updated2024-05-01
local.scopus.urlhttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=36949016238&origin=inward
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