Forensic determination of crossing lines involving stamp and pen inks by mass spectrometry imaging
Tipo
Artigo
Data de publicação
2020
Periódico
Analytical Methods
Citações (Scopus)
11
Autores
Rodrigues De Morais D.
Campelo J.D.M.
Razzo D.
Eberlin M.N.
Costa J.L.
Santos J.M.
Campelo J.D.M.
Razzo D.
Eberlin M.N.
Costa J.L.
Santos J.M.
Orientador
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Título de Volume
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Resumo
© The Royal Society of Chemistry 2020.One of the most challenging tasks in forensic cases is to identify the intersection sequence of lines and inks in questionable documents, mainly in those involving significant financial values such as insurance claims, wills and contracts. Optical examination using microscopy images has been commonly used, but this morphological examination presents severe limitations that can lead to false conclusions. Herein, we show that mass spectrometry imaging (MSI) using easy ambient sonic-spray ionization (EASI) can be used to accurately identify the sequence of lines at intersecting points between stamp and pen inks. First, we used proof of concept cases and ion images, and extracted ion chronograms and EASI-MS profiles to evaluate how they could identify the intersection sequences. EASI-MSI was then used to distinguish the sequence of intersecting lines in two cases of simulated contract documents in which a signature made from pen ink was placed under or above the stamp ink. We demonstrate that EASI-MSI provided a clear indication of the actual sequence, showing that it functions as an efficient and rather unequivocal analytical tool in the examination of crossing ink lines when stamping is involved.
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Assuntos Scopus
Contract document , Easy ambient sonic spray ionizations , Financial values , Insurance claims , Mass spectrometry imaging (MSI) , Mass-spectrometry imaging , Microscopy images , Proof of concept